Cold Monarch Barbarian

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This build is pretty well fleshed out in terms of its DPS. If you get max dmg reduction while wearing natashas, it might be worth it, only if your defense is the same w/o bear stance. IMO DPS with iceburst is so high with -100 pierce that crushing blow and IAS from wolf isnt noticeable. Also, in MXL survivabiltiy is the key, and bear stance certainly pnrovides more of that. One thing you could try, is using Dual WIeld axe set. You sacrifice in Defense somewhat, but your rainbow damage increase, thanks to Oskill nephilim weapons. (see above)
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The rainbow damage will be fairly negligible without triple elemental pierce to make it even barely strong, let alone getting -135% to fire and lightning with the cold pierce.

Try
Qarak's Will
Qarak's Will
Giant Sword (Sacred)

One-Hand Damage: (152-163) to (234-246)
Two-Hand Damage: (208-226) to (288-306)
Required Strength: 480
Required Level: 100
Current Strength Damage Bonus: (76/256 per Strength)%
15% Chance to cast level 58 Pentagram on Melee Attack
25% Chance to cast level 34 Spike Nova on Melee Attack
10% Chance to cast level 36 Bloodlust when you Kill an Enemy
+250% Bonus Damage to Bloodlust
+(144 to 171)% Enhanced damage
Adds 50-125 damage
Adds 167-334 fire damage
+(26 to 38)% to Fire Spell Damage
17% Reanimate as: Flesh Clan
+333 Life after each Kill
Socketed (4)

or a nice
Shark (Xis)

Shark
Weapons

'TalXis'
Runeword Level: 121
1% Chance to cast level 31 Bloodlust when you Kill an Enemy
+(201 to 250)% Bonus Damage to Bloodlust
50% Increased Attack Speed
+230% Enhanced damage
+(3.25 per level) to Maximum Damage (Based on Character Level)
66% Chance of Open Wounds
+5 to all Attributes
-500 to Mana
for the bloodlust boosts or
Durandal the Blazing Sword
Durandal the Blazing Sword
Giant Sword (Sacred)

One-Hand Damage: (214-226) to (322-335)
Two-Hand Damage: (276-295) to (382-401)
Required Strength: 480
Required Level: 100
Current Strength Damage Bonus: (76/256 per Strength)%
25% Chance to cast level 13 Earthquake on Melee Attack
+(2 to 3) to Barbarian Skill Levels
(40 to 50)% Faster Run/Walk
25% Increased Attack Speed
+(172 to 200)% Enhanced damage
Adds 100-200 damage
(100 to 150)% Bonus to Attack Rating
+100 to Strength
Total Character Defense Plus (50 to 100)%
3% Reanimate as: Void Archon
Socketed (4)

for reanimates, wdm proc, and more defense amongst other things with a high def gilded shield craft or runeword with the Gladiator's Dominance oskill for max block. Even
Carsomyr
Carsomyr
Flamberge (Sacred)

One-Hand Damage: (225-238) to (311-325)
Two-Hand Damage: (304-325) to (384-406)
Required Strength: 540
Required Level: 100
Current Strength Damage Bonus: (76/256 per Strength)%
25% Chance to cast level 13 Shower of Rocks when you Kill an Enemy
50% Increased Attack Speed
+(172 to 200)% Enhanced damage
Adds 100-175 damage
100% Bonus to Attack Rating
+(40 to 50) to Strength
+(40 to 50) to Vitality
Damage Reduced by 10%
(1 to 2)% Reanimate as: Umbaru Spirit
+250 Life after each Kill
Socketed (6)

can be nice though it focuses more on physical damage than cold, it will convert to cold and give you some DR and reanimates too, while still allowing a shield.

There's a ton of options, and you wont even need 25+ points into bear stance with that setup to put you at the 50% DR Cap and 75% max block too.